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41.
Xuewu Li Lin Zhang Tian Shi Weining Yu Jinhui Shao Xuegang Zhou Yuxing He Binbin Zhang 《工业材料与腐蚀》2021,72(5):951-959
Ti-based amorphous metallic glasses have excellent mechanical, physical, and chemical properties, which is an important development direction and research hotspot of metal composite reinforcement. As a stable, simple, efficient, and large-scale preparation technology of metallic powders, the gas atomization process provides an effective way of preparing amorphous metallic glasses. In this study, the controllable fabrication of a Ti-based amorphous powder, with high efficiency, has been realized by using gas atomization. The scanning electron microscope, energy-dispersive spectrometer, and X-ray diffraction are used to analyze surface morphology, element distribution, and phase structure, respectively. A microhardness tester is used to measure the mechanical property. An electrochemical workstation is used to characterize corrosion behavior. The results show that as-prepared microparticles are more uniform and exhibit good amorphous characteristics. The mechanical test shows that the hardness of amorphous powder is significantly increased as compared with that before preparation, which has the prospect of being an important part of engineering reinforced materials. Further electrochemical measurement shows that the corrosion resistance of the as-prepared sample is also significantly improved. This study has laid a solid foundation for expanding applications of Ti-based metallic glasses, especially in heavy-duty and corrosive domains. 相似文献
42.
Mei Ying Liu Tu Lai Sun Xiao Li Zhu Xiao Qiang Liu He Tian Xiang Ming Chen 《Journal of the American Ceramic Society》2021,104(12):6393-6403
Hexagonal rare-earth ferrites (h-RFeO3) have attracted much scientific attention due to their room-temperature multiferroicity. However, it is still a hard job to obtain h-RFeO3 bulk materials because of the meta-stability of such hexagonal phase, and the evaluation of room-temperature ferroelectric and magnetoelectric characteristics in such materials is also a challengeable issue. In the present work, Yb1−xInxFeO3 ceramics with the stable hexagonal structure were obtained by introducing chemical pressure, where the unique ferroelectric domain structures of sixfold vortex combined with tenfold vortex with a typical size of ~400 nm were determined. Symmetry of the present system evolved from centrosymmetric orthorhombic Pbnm (x = 0–0.4) to non-centrosymmetric hexagonal P63cm (x = 0.5 and 0.6) with a ferroelectric polarization up to 3.2 μC/cm2, and finally to centrosymmetric hexagonal P63/mmc (x = 0.7 and 0.8). The Curie point decreased monotonically from 723 K to a temperature below room temperature with increasing x, and the antiferromagnetic phase transition above room temperature was determined for all compositions. Meanwhile, a large linear magnetoelectric coefficient (αME) up to 0.96 mV/cm Oe was obtained at room temperature, and this indicated the great application potential for magnetoelectric devices. 相似文献
43.
44.
Yongling An Yuan Tian Kai Zhang Yongpeng Liu Chengkai Liu Shenglin Xiong Jinkui Feng Yitai Qian 《Advanced functional materials》2021,31(26):2101886
Anode-free zinc batteries (AFZBs) are proposed as promising energy storage systems due to their high energy density, inherent safety, low cost, and simplified fabrication process. However, rapid capacity fading caused by the side reactions between the in situ formed zinc metal anode and electrolyte hinders their practical applications. To address these issues, aqueous AFZBs enabled by electrolyte engineering to form a stable interphase are designed. By introducing a multifunctional zinc fluoride (ZnF2) additive into the electrolyte, a stable F-rich interfacial layer is formed. This interfacial layer can not only regulate the growth orientation of zinc crystals, but also serve as an inert protection layer against side reactions such as H2 generation. Based on these synergy effects, zinc deposition/dissolution with high reversibility (Coulombic efficiency > 99.87%) and stable cycling performance up to 600 h of are achieved in the electrolyte optimized by ZnF2. With this electrolyte, the cycling life of AFZBs is significantly improved. The work may initiate the research of AFZBs and be useful for the design of high energy, high safety, and low-cost power sources. 相似文献
45.
Ningqin Deng He Tian Jian Zhang Jinming Jian Fan Wu Yang Shen Yi Yang Tian-Ling Ren 《半导体学报》2021,42(8):21-33
Black phosphorus(BP),an emerging two-dimensional material,is considered a promising candidate for next-genera-tion electronic and optoelectronic devices due to in-plane anisotropy,high mobility,and direct bandgap.However,BP devices face challenges due to their limited stability,photo-response speed,and detection range.To enhance BP with powerful electric-al and optical performance,the BP heterostructures can be created.In this review,the state-of-the-art heterostructures and their electrical and optoelectronic applications based on black phosphorus are discussed.Five parts introduce the perform-ance of BP-based devices,including black phosphorus sandwich structure by hBN with better stability and higher mobility,black phosphorus homojunction by dual-gate structure for optical applications,black phosphorus heterojunction with other 2D materials for faster photo-detection,black phosphorus heterojunction integration with 3D bulk material,and BP via As-doping tunable bandgap enabling photo-detection up to 8.2 μm.Finally,we discuss the challenges and prospects for BP electric-al and optical devices and applications. 相似文献
46.
47.
Jinrui Guo Zhi Su Jing Tian Jinhua Deng Tao Fu Yong Liu 《International Journal of Hydrogen Energy》2021,46(5):3453-3463
Hydrogen generation by the reaction of micrometer-aluminum powder with water at room temperature is hard to proceed due to the inhibition of alumina layer. In this study, a novel strategy of metal salts mediated Al-water reaction was proposed for more efficient and practical hydrogen generation. The effects of metal salt composition and dosage, and water injection rate and volume on hydrogen generation were investigated. The hydrogen yield of 230.0 mL was achieved in the Al/Ni/Cu/H2O system within 600 s under the following conditions: 0.24 g aluminum with the molar ratio of Al, Ni and Cu at 10:1:1 and 2 mL water at the injection rate of 2 mL/min, which was equivalent to 70.4% of the theoretical hydrogen yield. Based on the morphology, element composition, crystal structure and electrochemical test results of the obtained composites after reaction, the mechanism of hydrogen production by metal salts mediated Al-water reaction was proposed. 相似文献
48.
Hiromi Eba Yuki Masuzoe Toru Sugihara Hayao Yagi Tian Liu 《International Journal of Hydrogen Energy》2021,46(18):10642-10652
Ammonia generation was studied in the reaction between water and nitrogen-containing iron at 323 K and atmospheric pressure. Similar to metallic Fe, the interstitial compound Fe3N reduced water through Fe oxidation to produce hydrogen gas, while the N combined with atomic hydrogen to produce ammonia as a byproduct. The addition of carbon dioxide to this system accelerated the reaction with concomitant consumption of carbon dioxide. The promoted ammonia production upon addition of carbon dioxide can be attributed to the generation of atomic hydrogen from the redox reaction of carbonic acid and Fe, as well as removal of used Fe from the reaction system through the formation of a soluble carbonato complex. When carbonate was added to the reaction system, the production rates of ammonia and hydrogen increased further. The results here confirmed that ammonia can be synthesized from iron nitride under mild conditions by utilizing carbon dioxide. 相似文献
49.
三门峡水库汛期排沙效果研究 总被引:2,自引:2,他引:0
三门峡水库汛期排沙是解决泥沙淤积问题、控制潼关高程的关键途径。"蓄清排浑"运用以来,非汛期蓄水期库区发生淤积、汛期降低水位运用排泄全年泥沙,基本保持了库区动态冲淤平衡。不同控制水位和入库流量过程存在不同的排沙效果,针对三门峡水库汛期排沙过程的差异,对"蓄清排浑"运用以来汛期排沙特征进行统计,分析了水库敞泄和不同控制水位运用对排沙效果的影响。结果表明,在汛期平水305 m、洪水敞泄的运用条件下,水库排沙具有多来多排的特点,汛期排沙总量与入库含沙量和水量密切相关;完全敞泄时库区冲刷取决于流量大小和敞泄时间,净排沙效率随着水量的增加和敞泄时间的延长而减小,冲刷效率降低;汛期控制运用期,当流量在1000 m~3/s以上时、水位在305~311 m也会产生一定的排沙,排沙效果取决于含沙水流在壅水段的滞留时间和出入库流量之比。研究成果可为三门峡水库运用方式的优化提供依据。 相似文献
50.
近年来,世界范围内的工业化和城市化进程明显加快,环境污染是全球性的危机。在我国的环保工作开展中,环境影响评价和排污许可是有效的环保工作手段,这两种手段的有效配合,分别从准入和运营的角度来实现了污染的有效控制,虽然环境影响评价在我国实施的时间非常长,但是,排污许可却是近年来才出现的,出现时间的不一致导致二者在衔接和促进的过程中面临着较大的困境。因此,针对这一情况,本文充分探析了环评和排污许可相互衔接和促进的策略。 相似文献